21. Anne Hathaway
In 2012 actress Anne Hathaway married her longtime boyfriend, jewelry designer Adam Shulman, and the Princess Diaries star looked like a proper princess. Her gown was a custom-made Valentino dress, designed by Valentino himself, but perhaps the most eye-catching part of her attire wasn’t even the dress, but her long veil and vintage-inspired headpiece.
The dress, although extravagant, features delicate work of lace and embroidery, as does the headpiece. Only a handful of people got the pleasure to see the dress from up close, as the guest list included only close friends and family of the couple, and almost no coworkers or friends from the entertainment industry.
