Actors Brad Pitt and Gwyneth Paltrow
On the set of the 1990s psychological thriller, Seven, these A-listers became acquainted. After proposing to Paltrow, Pitt married her in 1996.

However, things didn’t work out and the pair parted up before they could consummate their relationship. Brad was “too good” for Gwyneth Paltrow, she later said.